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姓 名：邓罡华 职 称：特聘研究员 职 务：教师 办 公 室：主楼308 电子邮件：ghdeng@bupt.edu.cn |
个人简介：2006年于中国科学技术大学化学物理系获理学学士学位，2013年于中国科学技术大学微尺度物质科学国家实验室物理化学专业获理学博士学位，2013年-2017年于中国科学院大连化学物理研究所杨学明院士课题组从事博士后研究工作，2017年-2020年于美国犹他州立大学化学系Yi Rao教授课题组从事博士后研究工作，2020年-2022年于美国俄亥俄州立大学化学系L. Robert Baker教授课题组从事博士后研究工作，2022年加入北京邮电大学理学院。
研究方向：超快光谱学，多维界面光谱，凝聚相及界面的超快动力学，光电材料中的超快动力学
科研项目：
代表性科研成果：
成功设计开发了二维电子和频光谱与二维电子-振动和频光谱两种全新的界面多维光谱技术，将界面二维和频光谱技术从分子振动波段拓展至电子态波段，是界面多维光谱领域的突破性进展。利用这些界面非线性光谱/超快光谱系统，在有机/无机半导体的激发态动力学、溶液的体相与界面微观结构与动力学和二氧化碳在电极界面的电化学还原等方面取得了系列成果：
1. Q. Zhu, S.K. Wallentine, G.H. Deng, J. A. Rebstock, and L.R. Baker*, The Solvation-Induced Onsager Reaction Field Rather than the Double-Layer Field Controls CO2 Reduction on Gold, JACS Au, 2022, 2, 472–482
2. G.H. Deng, Y. Qian, T. Zhong, J. Han, H. Chen, Y. Rao*, Two-Dimensional Electronic-Vibrational Sum Frequency Spectroscopy for Interactions of Electronic and Nuclear Motions at Interfaces, Proc. Natl. Acad. Sci. U.S.A., 2021, 118, e2100608118.
3. G.H. Deng, Y. Qian, X. Li, T. Zhong, W. Jiang, R. Harutyunyan, G. Chen*, H. Chen*, Y. Rao*, Singlet Fission Driven by Anisotropic Vibronic Coupling in Single-Crystalline Pentacene, J. Phys. Chem. Lett., 2021, 12, 3142-3150
4. G.H Deng, Q. Wei, Y. Qian, T Zhang, X. Leng, Y. Rao*, Development of interface-/surface-specific two-dimensional electronic spectroscopy, Rev. Sci. Instrum, 2021, 92, 023104
5. Y. Qian, G.H. Deng, Y Rao*, In Situ Spectroscopic Probing of Polarity and Molecular Configuration at Aerosol Particle Surfaces, J. Phys. Chem. Lett., 2020, 11, 6763-6771
6. J. Han, Q. Xie, J. Luo, G.H. Deng, Y. Qian, D. Sun, A.R. Harutyunyan, G. Chen, and Y. Rao*, Anisotropic Geminate and Non-Geminate Recombination of Triplet Excitons in Singlet Fission of Single Crystalline Hexacene, J. Phys. Chem. Lett., 2020, 11, 4, 1261–1267
7. G.H. Deng, Y. Qian, T. Zhang, Y. Rao*, Interface-Specific Two-Dimensional Electronic Sum Frequency Generation Spectroscopy, J. Phys. Chem. Lett., 2020, 11, 1738-1745.
8. G.H. Deng, Y. Shen, H. Chen, Y. Chen, B. Jiang, G. Wu, X. Yang, K. Yuan* and J. Zheng*, Ordered-to-Disordered Transformation of Enhanced Water Structure on Hydrophobic Surfaces in Concentrated Alcohol–Water Solutions, J. Phys. Chem. Lett., 2019, 10, 24, 7922-7928
9. D. Sun#, G.H. Deng #, B. Xu#, E. Xu#, X. Li, Y. Wu, Y. Qian, Y. Zhong, C. Nuckolls, A. R. Harutyunyan, H.L. Dai, G. Chen*, H. Chen*, Y. Rao*, Anisotropic Singlet Fission in Single Crystalline Hexacene, iScience, 2019, 19, 1079–1089
10. G.H. Deng, Q. Wei, J. Han, Y. Qian, J. Luo, A. R. Harutyunyan, G. Chen, H. Bian*, H. Chen*, Y. Rao*, Vibronic Fingerprint of Singlet Fission in Hexacene. J. Chem. Phys., 2019, 151, 054703.
11. Y. Qian, G.H. Deng, J. Lapp, Y. Rao*, Interfaces of Gas–Aerosol Particles: Relative Humidity and Salt Concentration Effects. J. Phys. Chem. A, 2019, 123, 6304-6312.
12. G.H. Deng, Y. Qian, Y. Rao*, Development of Ultrafast Broadband Electronic Sum Frequency Generation for Charge Dynamics at Surfaces and Interfaces. J. Chem. Phys., 2019, 150, 024708.
13. Y. Rao*, Y. Qian, G.H. Deng, A. Kinross, N. J. Turro, K. B. Eisenthal*, Molecular Rotation in 3 Dimensions at an Air/Water Interface Using Femtosecond Time Resolved Sum Frequency Generation. J. Chem. Phys., 2019, 150, 094709.
14. Y. Qian, G.H. Deng, Y. Rao*, In Situ Chemical Analysis of the Gas–Aerosol Particle Interface. Anal. Chem., 2018, 90, 10967-10973.
15. G.H. Deng, Y.N. Shen, Z.G He, Q. Zhang, B. Jiang, K.J. Yuan*, G.R. Wu and X.M. Yang, The molecular rotational motion of liquid ethanol studied by ultrafast time resolved infrared spectroscopy, Phys. Chem. Chem. Phys., 2017, 19, 4345-4351
16. G.H. Deng, X. Li, S.L. Liu*, Z. Zhang, Z. Lu, Y. Guo*, Successive Adsorption of Cations and Anions of Water-1-Butyl-3-Methylimidazolium Methylsulfate Binary Mixtures at the Air-Liquid Interface Studied by Sum Frequency Generation Vibrational Spectroscopy and Surface Tension Measurements. J. Phys. Chem. C, 2016, 120, 12032-12041.
17. Y.N. Shen#, G.H. Deng#, C.Q. Ge, Y.H. Tian, G.R. Wu, X.M. Yang, J.R. Zheng, K.J. Yuan*, Solvation Structure around the Li+ Ion in Succinonitrile-Lithium Salt Plastic Crystalline Electrolytes. Phys. Chem. Chem. Phys., 2016, 18, 14867-14873. (#equal contribution)
18. C.Q. Ge, Y.N. Shen, G.H. Deng, Y.H. Tian, D.Q. Yu, X.M. Yang, K.J. Yuan*, J.R. Zheng*, Negligible Isotopic Effect on Dissociation of Hydrogen Bonds. J. Phys. Chem. B, 2016, 120, 3187−3195
19. Y. N. Shen; B. Jiang; C. Q. Ge; G.H. Deng; H.L. Chen; X.M. Yang; K. J. Yuan*; J. R. Zheng*, Intermolecular Vibrational Energy Transfers in Melts and Solutions. Chin. J. Chem. Phys., 2016, 29, 407-417.
20. X. Li, G.H. Deng, R.J. Feng, K. Lin, Z. Zhang, Y. Bai, Z. Lu*, Y. Guo*, Salt Effect on Molecular Orientation at Air/Liquid Methanol Interface. Chin. Chem. Lett., 2016, 27, 535-539
21. Y.N. Shen, T.M. Wu, B. Jiang, G.H. Deng, J.B. Li, H.L. Chen, X.M. Guo, C.Q. Ge, Y.J. Chen, J.Y. Hong, X.M. Yang, K.J. Yuan*, W. Zhuang* and J.R. Zheng*, Comparison Studies on Sub-Nanometer-Sized Ion Clusters in Aqueous Solutions: Vibrational Energy Transfers, MD Simulations, and Neutron Scattering, J. Phys. Chem. B, 2015, 119, 9893-9904.
22. G.H. Deng, Y.Q. Guo, X. Li, Z. Zhang, S.L. Liu, Z. Lu* and Y. Guo*, Surface of room temperature ionic liquid [bmim][PF6] studied by polarization- and experimental configuration-dependent sum frequency generation vibrational spectroscopy, Sci. China Chem., 2015, 58, 439-447.
23. A.A. Liu, Z. Huang, G.H. Deng and Y. Guo*, Adsorption of benzonitrile at the air/water interface studied by sum frequency generation spectroscopy, Chin. Sci. Bull., 2013, 58, 1529-1535.
24. G.H. Deng, X. Li, Y.Q. Guo, S.L. Liu, Z. Lu* and Y. Guo*, Orientation and Structure of Ionic Liquid Cation at Air/ bmirn BF4 Aqueous Solution Interface, Chin. J. Chem. Phys., 2013, 26, 569-575.
25. G.H. Deng, H.F. Wang and Y. Guo*, Nonlinear Optical Spectroscopy Studies on Water and Electrolyte Aqueous Solution Interfaces-Specific Ion Effect at Air/Electrolyte Aqueous Solution Interfaces, Prog. Chem., 2012, 24, 1865-1879.
26. 黄芝, 唐鑫, 邓罡华, 周恩财, 王鸿飞, 郭源*, 和频振动光谱研究多晶金电极/溶液界面乙腈分子取向的flip-flop行为, 电化学, 2011, 134-138.
27. Y. Wang, G.H. Deng and Y. Guo*, Analysis and Simulation of Experimental Configurations for Sum Frequency Generation and Difference Frequency Generation Vibrational Spectroscopy, Acta Phys. Chim. Sin., 2011, 27, 2733-2742.
28. D. Wu, G.H. Deng, Y. Guo and H.F. Wang*, Observation of the Interference between the Intramolecular IR-Visible and Visible-IR Processes in the Doubly Resonant Sum Frequency Generation Vibrational Spectroscopy of Rhodamine 6G Adsorbed at the Air/Water Interface, J. Phys. Chem. A, 2009, 113, 6058-6063.
